The hosts satirically answer several questions of barangay residents who seek resolution to their problems. Homeviewers may email their problem or directly call the hosts to share their problem on air. The barangay hosts also attempt to answer questions that netizens ask through the show's Twitter or Facebook page. The netizens may also offer answers or solutions to the chosen “problem of the day.” Popular characters popularized by the segment include Doktora Dora de Explorer and Lola Nidora.

Eventually, Problem Solving gave birth to the phenomenal loveteam called AlDub, and the segment gradually morphed into a live impromptu soap opera called Kalyeserye.

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